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Her legacy became cemented after her extraordinary meeting with French Emperor Napoleon I at Tilsit — she met with him to plead unsuccessfully for favorable terms after Prussia 's disastrous losses in the War of the Fourth Coalition. She was already well loved by her subjects, but her meeting with Napoleon led Louise to become revered as "the soul of national virtue".
Her early death at the age of thirty-four "preserved her youth in the memory of posterity", and caused Napoleon to reportedly remark that the king "has lost his best minister". The Order of Louise was founded by her grieving husband four years later as a female counterpart to the Iron Cross. In the s, conservative German women founded the Queen Louise League.
Her maternal grandmother, Princess Maria Louise of Hesse-Darmstadt , and her paternal first-cousin Princess Augusta Sophia of the United Kingdom served as sponsors at her baptism; her second given name came from Princess Augusta Sophia.
At the time of her birth, Louise's father was not yet the ruler of Mecklenburg-Strelitz he would not succeed his brother as duke until , and consequently she was not born in a court, but rather in a less formal home. Louise was particularly close to her sister Frederica , who was two years younger, as well as with their only brother George. Louise and her aunt and new stepmother became close until Charlotte's early death the year after their marriage, also from childbirth complications.